Materials Science and Engineering

Ilmu material atau teknik material atau ilmu bahan adalah sebuah interdisiplin ilmu teknik yang mempelajari tentang sifat bahan dan aplikasinya terhadap berbagai bidang ilmu dan teknik (khususnya bidang Teknik Mesin). Ilmu ini mempelajari hubungan antara struktur bahan dan sifatnya. Yang termasuk dalam ilmu ini adalah unsur fisika terapan, teknik kimia, teknik mesin, teknik sipil dan teknik listrik. Ilmu material juga mempelajari teknik proses atau fabrikasi (pengecoran, pengerolan, pengelasan, dan lain-lain), teknik analisa, kalorimetri, mikroskopi optik dan elektron, dan lain-lain), serta analisa biaya atau keuntungan dalam produksi material untuk industri. Perkembangan terakhir, ilmu tentang bahan ini mendapat sumbangan yang besar dari majunya bidang nanoteknologi dan mulai diajarkan secara luas di banyak universitas.

Materials science is an interdisciplinary field applying the properties of matter to various areas of science and engineering. This scientific field investigates the relationship between the structure of materials at atomic or molecular scales and their macroscopic properties. It incorporates elements of applied physics and chemistry. With significant media attention focused on nanoscience and nanotechnology in recent years, materials science has been propelled to the forefront at many universities. It is also an important part of forensic engineering and failure analysis. Materials science also deals with fundamental properties and characteristics of materials.

Fundamentals

The basis of materials science involves relating the desired properties and relative performance of a material in a certain application to the structure of the atoms and phases in that material through characterization. The major determinants of the structure of a material and thus of its properties are its constituent chemical elements and the way in which it has been processed into its final form. These characteristics, taken together and related through the laws of thermodynamics, govern a material’s microstructure, and thus its properties.

The manufacture of a perfect crystal of a material is currently physically impossible. Instead materials scientists manipulate the defects in crystalline materials such as precipitates, grain boundaries (Hall-Petch relationship), interstitial atoms, vacancies or substitutional atoms, to create materials with the desired properties.

Not all materials have a regular crystal structure. Polymers display varying degrees of crystallinity, and many are completely non-crystalline. Glasses, some ceramics, and many natural materials are amorphous, not possessing any long-range order in their atomic arrangements. The study of polymers combines elements of chemical and statistical thermodynamics to give thermodynamic, as well as mechanical, descriptions of physical properties.

In addition to industrial interest, materials science has gradually developed into a field which provides tests for condensed matter or solid state theories. New physics emerge because of the diverse new material properties which need to be explained.

Materials in industry

Radical materials advances can drive the creation of new products or even new industries, but stable industries also employ materials scientists to make incremental improvements and troubleshoot issues with currently used materials. Industrial applications of materials science include materials design, cost-benefit tradeoffs in industrial production of materials, processing techniques (casting, rolling, welding, ion implantation, crystal growth, thin-film deposition, sintering, glassblowing, etc.), and analytical techniques (characterization techniques such as electron microscopy, x-ray diffraction, calorimetry, nuclear microscopy (HEFIB), Rutherford backscattering, neutron diffraction, small-angle X-ray scattering (SAXS), etc.

Besides material characterization, the material scientist/engineer also deals with the extraction of materials and their conversion into useful forms. Thus ingot casting, foundry techniques, blast furnace extraction, and electrolytic extraction are all part of the required knowledge of a metallurgist/engineer. Often the presence, absence or variation of minute quantities of secondary elements and compounds in a bulk material will have a great impact on the final properties of the materials produced, for instance, steels are classified based on 1/10 and 1/100 weight percentages of the carbon and other alloying elements they contain. Thus, the extraction and purification techniques employed in the extraction of iron in the blast furnace will have an impact of the quality of steel that may be produced.

The overlap between physics and materials science has led to the offshoot field of materials physics, which is concerned with the physical properties of materials. The approach is generally more macroscopic and applied than in condensed matter physics. See important publications in materials physics for more details on this field of study.

Metal alloys

The study of metal alloys is a significant part of materials science. Of all the metallic alloys in use today, the alloys of iron (steel, stainless steel, cast iron, tool steel, alloy steels) make up the largest proportion both by quantity and commercial value. Iron alloyed with various proportions of carbon gives low, mid and high carbon steels. For the steels, the hardness and tensile strength of the steel is directly related to the amount of carbon present, with increasing carbon levels also leading to lower ductility and toughness. The addition of silicon and graphitization will produce cast irons (although some cast irons are made precisely with no graphitization). The addition of chromium, nickel and molybdenum to carbon steels (more than 10%) gives us stainless steels.

Other significant metallic alloys are those of aluminium, titanium, copper and magnesium. Copper alloys have been known for a long time (since the Bronze Age), while the alloys of the other three metals have been relatively recently developed. Due to the chemical reactivity of these metals, the electrolytic extraction processes required were only developed relatively recently. The alloys of aluminium, titanium and magnesium are also known and valued for their high strength-to-weight ratios and, in the case of magnesium, their ability to provide electromagnetic shielding. These materials are ideal for situations where high strength-to-weight ratios are more important than bulk cost, such as in the aerospace industry and certain automotive engineering applications. 

Polymers

Polymers are also an important part of materials science. Polymers are the raw materials (the resins) used to make what we commonly call plastics. Plastics are really the final product, created after one or more polymers or additives have been added to a resin during processing, which is then shaped into a final form. Polymers which have been around, and which are in current widespread use, include polyethylene, polypropylene, PVC, polystyrene, nylons, polyesters, acrylics, polyurethanes, and polycarbonates. Plastics are generally classified as "commodity", "specialty" and "engineering" plastics.

PVC (polyvinyl-chloride) is widely used, inexpensive, and annual production quantities are large. It lends itself to an incredible array of applications, from artificial leather to electrical insulation and cabling, packaging and containers. Its fabrication and processing are simple and well-established. The versatility of PVC is due to the wide range of plasticisers and other additives that it accepts. The term "additives" in polymer science refers to the chemicals and compounds added to the polymer base to modify its material properties.

Polycarbonate would be normally considered an engineering plastic (other examples include PEEK, ABS). Engineering plastics are valued for their superior strengths and other special material properties. They are usually not used for disposable applications, unlike commodity plastics.

Specialty plastics are materials with unique characteristics, such as ultra-high strength, electrical conductivity, electro-fluorescence, high thermal stability, etc.

The dividing lines between the various types of plastics is not based on material but rather on their properties and applications. For instance, polyethylene (PE) is a cheap, low friction polymer commonly used to make disposable shopping bags and trash bags, and is considered a commodity plastic, whereas Medium-Density Polyethylene MDPE is used for underground gas and water pipes, and another variety called Ultra-high Molecular Weight Polyethylene UHMWPE is an engineering plastic which is used extensively as the glide rails for industrial equipment and the low-friction socket in implanted hip joints.

Ceramics and glasses

Another application of the material sciences is the structures of glass and ceramics, typically associated with the most brittle materials. Bonding in ceramics and glasses are using covalent and ionic-covalent types with SiO2, silica or sand, as a fundamental building block. Ceramics are as soft as clay and as hard as stone and concrete. Usually, they are crystalline in form. Most glasses contain a metal oxide fused with silica. At high temperatures used to prepare glass, the material is a viscous liquid. The structure of glass forms into an amorphous state upon cooling. Windowpanes and eyeglasses are important examples. Fibers of glass are also available. Diamond and carbon in its graphite form are considered to be ceramics.

Engineering ceramics are known for their stiffness, high temperature, and stability under compression and electrical stress. Alumina, silica carbide, and tungsten carbide are made from a fine powder of their constituents in a process of sintering with a binder. Hot pressing provides higher density material. Chemical vapor deposition can place a film of a ceramic on another material. Cermets are ceramic particles containing some metals. The wear resistance of tools is derived from cemented carbides with the metal phase of cobalt and nickel typically added to modify properties.

Composite materials

Another application of material science in industry is the making of composite materials. Composite materials are structured materials composed of two or more macroscopic phases. Applications range from structural elements such as steel-reinforced concrete, to the thermally insulative tiles which play a key and integral role in NASA's Space Shuttle thermal protection system which is used to protect the surface of the shuttle from the heat of re-entry into the Earth's atmosphere. One example is Reinforced Carbon-Carbon (RCC), The light gray material which withstands re-entry temperatures up to 1510 °C (2750 °F) and protects the Space Shuttle's wing leading edges and nose cap. RCC is a laminated composite material made from graphite rayon cloth and impregnated with a phenolic resin. After curing at high temperature in an autoclave, the laminate is pyrolized to convert the resin to carbon, impregnated with furfural alcohol in a vacuum chamber, and cured/pyrolized to convert the furfural alcohol to carbon. In order to provide oxidation resistance for reuse capability, the outer layers of the RCC are converted to silicon carbide.

Other examples can be seen in the "plastic" casings of television sets, cell-phones and so on. These plastic casings are usually a composite material made up of a thermoplastic matrix such as acrylonitrile-butadiene-styrene (ABS) in which calcium carbonate chalk, talc, glass fibres or carbon fibres have been added for added strength, bulk, or electro-static dispersion. These additions may be referred to as reinforcing fibres, or dispersants, depending on their purpose.

Classes of materials

Materials science encompasses various classes of materials, each of which may constitute a separate field. Materials are sometimes classified by the type of bonding present between the atoms:

1. Ionic crystals
2. Covalent crystals
3. Metals
4. Intermetallics
5. Semiconductors
6. Polymers
7. Composite materials
8. Vitreous materials

  Overview

• Nanotechnology – rigorously, the study of materials where the effects of quantum confinement, the Gibbs-Thomson effect, or any other effect only present at the nanoscale is the defining property of the material; but more commonly, it is the creation and study of materials whose defining structural properties are anywhere from less than a nanometer to one hundred nanometers in scale, such as molecularly engineered materials.
• Microtechnology - study of materials and processes and their interaction, allowing microfabrication of structures of micrometric dimensions, such as MicroElectroMechanical Systems (MEMS).
• Crystallography – the study of how atoms in a solid fill space, the defects associated with crystal structures such as grain boundaries and dislocations, and the characterization of these structures and their relation to physical properties.
• Materials Characterization – such as diffraction with x-rays, electrons, or neutrons, and various forms of spectroscopy and chemical analysis such as Raman spectroscopy, energy-dispersive spectroscopy (EDS), chromatography, thermal analysis, electron microscope analysis, etc., in order to understand and define the properties of materials. See also List of surface analysis methods

Si₃N₄ ceramic bearing parts

Si₃N₄ ceramic bearing parts

• Metallurgy – the study of metals and their alloys, including their extraction, microstructure and processing.
• Biomaterials – materials that are derived from and/or used with biological systems.
• Electronic and magnetic materials – materials such as semiconductors used to create integrated circuits, storage media, sensors, and other devices.
• Tribology – the study of the wear of materials due to friction and other factors.
• Surface science/Catalysis – interactions and structures between solid-gas solid-liquid or solid-solid interfaces.
• Ceramography – the study of the microstructures of high-temperature materials and refractories, including structural ceramics such as RCC, polycrystalline silicon carbide and transformation toughened ceramics

Some practitioners often consider rheology a sub-field of materials science, because it can cover any material that flows. However, modern rheology typically deals with non-Newtonian fluid dynamics, so it is often considered a sub-field of continuum mechanics. See also granular material.

A cloth of woven carbon fiber filaments is commonly used for reinforcement in composite materials

• Glass Science – any non-crystalline material including inorganic glasses, vitreous metals and non-oxide glasses.
• Forensic engineering – the study of how products fail, and the vital role of the materials of construction
• Forensic materials engineering – the study of material failure, and the light it sheds on how engineers specify materials in their product
• Textile Reinforced Materials - materials in the form of ceramic or concrete are reinforced with a primarily woven or non-woven textile structure to impose high strength with comparatively more flexibility to withstand vibrations and sudden jerks.

Primary topics

• Thermodynamics, statistical mechanics, and physical chemistry, for phase equilibrium conditions, phase diagrams of materials systems (multi-phase, multi-component, reacting and non-reacting systems)
• Phase transformation kinetics, for the kinetics of phase transformations (with particular emphasis on solid-solid phase transitions)
• Transport phenomena for the transport of heat, mass, and momentum in materials processing.
• Crystallography, quantum chemistry or quantum physics, for the structure (symmetry and defects) and bonding in materials (e.g., ionic, metallic, covalent, and van der Waals bonding)
• Mechanical behavior of materials, to understand the mechanical properties of materials, defects and their propagation, and their behavior under static, dynamic, and cyclic loads
• Electronic properties of materials, and solid-state physics, for the understanding of the electronic, thermal, magnetic, and optical properties of materials
• Diffraction and wave mechanics, for the science behind characterization systems, e.g., transmission electron microscopy (TEM)

Household items made of various kinds of plastic

Household items made of various kinds of plastic.

• Polymer properties, synthesis, and characterization, for a specialized understanding of how polymers behave, how they are made, and how they are characterized; exciting applications of polymers include liquid crystal displays (LCDs, the displays found in most cell-phones, cameras, and iPods), novel photovoltaic devices based on semiconductor polymers (which, unlike the traditional silicon solar panels, are flexible and cheap to manufacture, albeit with lower efficiency), and membranes for room-temperature fuel cells (as proton exchange membranes) and filtration systems in the environmental and biomedical fields
• Biomaterials, physiology, biomechanics, biochemistry, for a specialized understanding of how materials integrate into biological systems, e.g., through materiomics
• Semiconductor materials and semiconductor devices, for a specialized understanding of the advanced processes used in industry (e.g. crystal growth techniques, thin-film deposition, ion implantation, photolithography), their properties, and their integration in electronic devices
• Alloying, corrosion, and thermal or mechanical processing, for a specialized treatment of metallurgical materials—with applications ranging from aerospace and industrial equipment to the civil industries

Composite materials

Composite materials, often shortened to composites, are engineered or naturally occurring materials made from two or more constituent materials with significantly different physical or chemical properties which remain separate and distinct at the macroscopic or microscopic scale within the finished structure.

The very common example would be disc brake pads, which consists of hard ceramic particles embedded in soft metal matrix. Those composites closest to our personal hygiene form our shower stalls and bathtubs made of fibreglass. Imitation granite and cultured marble sinks and countertops are widely used. The most advanced examples perform routinely on spacecraft in demanding environments.

Composition

Plywood is a commonly encountered composite material.

Wood is a natural composite of Cellulose fibres in a matrix of lignin. The earliest man-made composite materials were straw and mud combined to form bricks for building construction. The ancient brick-making process can still be seen on Egyptian tomb paintings in the Metropolitan Museum of Art.

Composites are made up of individual materials referred to as constituent materials. There are two categories of constituent materials: matrix and reinforcement. At least one portion of each type is required. The matrix material surrounds and supports the reinforcement materials by maintaining their relative positions. The reinforcements impart their special mechanical and physical properties to enhance the matrix properties. A synergism produces material properties unavailable from the individual constituent materials, while the wide variety of matrix and strengthening materials allows the designer of the product or structure to choose an optimum combination.

Engineered composite materials must be formed to shape. The matrix material can be introduced to the reinforcement before or after the reinforcement material is placed into the mould cavity or onto the mould surface. The matrix material experiences a melding event, after which the part shape is essentially set. Depending upon the nature of the matrix material, this melding event can occur in various ways such as chemical polymerization or solidification from the melted state.

A variety of moulding methods can be used according to the end-item design requirements. The principal factors impacting the methodology are the natures of the chosen matrix and reinforcement materials. Another important factor is the gross quantity of material to be produced. Large quantities can be used to justify high capital expenditures for rapid and automated manufacturing technology. Small production quantities are accommodated with lower capital expenditures but higher labour and tooling costs at a correspondingly slower rate.

Most commercially produced composites use a polymer matrix material often called a resin solution. There are many different polymers available depending upon the starting raw ingredients. There are several broad categories, each with numerous variations. The most common are known as polyester, vinyl ester, epoxy, phenolic, polyimide, polyamide, polypropylene, PEEK, and others. The reinforcement materials are often fibres but also commonly ground minerals. The various methods described below have been developed to reduce the resin content of the final product, or the fibre content is increased. As a rule of thumb, lay up results in a product containing 60% resin and 40% fibre, whereas vacuum infusion gives a final product with 40% resin and 60% fibre content. The strength of the product is greatly dependent on this ratio.

Moulding methods

In general, the reinforcing and matrix materials are combined, compacted and processed to undergo a melding event. After the melding event, the part shape is essentially set, although it can deform under certain process conditions. For a thermoset polymeric matrix material, the melding event is a curing reaction that is initiated by the application of additional heat or chemical reactivity such as an organic peroxide. For a thermoplastic polymeric matrix material, the melding event is a solidification from the melted state. For a metal matrix material such as titanium foil, the melding event is a fusing at high pressure and a temperature near the melt point.

For many moulding methods, it is convenient to refer to one mould piece as a "lower" mould and another mould piece as an "upper" mould. Lower and upper refer to the different faces of the moulded panel, not the mould's configuration in space. In this convention, there is always a lower mould, and sometimes an upper mould. Part construction begins by applying materials to the lower mould. Lower mould and upper mould are more generalized descriptors than more common and specific terms such as male side, female side, a-side, b-side, tool side, bowl, hat, mandrel, etc. Continuous manufacturing processes use a different nomenclature.

The moulded product is often referred to as a panel. For certain geometries and material combinations, it can be referred to as a casting. For certain continuous processes, it can be referred to as a profile. Applied with a pressure roller, a spray device or manually. This process is generally done at ambient temperature and atmospheric pressure. Two variations of open moulding are Hand Layup and Spray-up.

Vacuum bag moulding

A process using a two-sided mould set that shapes both surfaces of the panel. On the lower side is a rigid mould and on the upper side is a flexible membrane or vacuum bag. The flexible membrane can be a reusable silicone material or an extruded polymer film. Then, vacuum is applied to the mould cavity. This process can be performed at either ambient or elevated temperature with ambient atmospheric pressure acting upon the vacuum bag. Most economical way is using a venturi vacuum and air compressor or a vacuum pump.

A vacuum bag is a bag made of strong rubber-coated fabric or a polymer film used to bond or laminate materials. In some applications the bag encloses the entire material, or in other applications a mold is used to form one face of the laminate with the bag being single sided to seal the outer face of the laminate to the mold. The open end is sealed and the air is drawn out of the bag through a nipple using a vacuum pump. As a result, uniform pressure approaching one atmosphere is applied to the surfaces of the object inside the bag, holding parts together while the adhesive cures. The entire bag may be placed in a temperature-controlled oven, oil bath or water bath and gently heated to accelerate curing.

In commercial woodworking facilities vacuum bags are used to laminate curved and irregular shaped workpieces.

Vacuum bagging is widely used in the composites industry as well. Carbon fiber fabric and fiberglass, along with resins and epoxies are common materials laminated together with a vacuum bag operation.

Typically, polyurethane or vinyl materials are used to make the bag, which is commonly open at both ends. This gives access to the piece, or pieces to be glued. A plastic rod is laid onto the bag, which is then folded over the rod. A plastic sleeve with an opening in it, is then snapped over the rod. This procedure forms a seal at both ends of the bag, when the vacuum is ready to be drawn.

A "platen" is used inside the bag for the piece being glued to lay on. The platen has a series of small slots cut into it, to allow the air under it to be evacuated. The platen must have rounded edges and corners to prevent the vacuum from tearing the bag.

When a curved part is to be glued in a vacuum bag, it is important that the pieces being glued be placed over a solidly built form, or have an air bladder placed under the form. This air bladder has access to "free air" outside the bag. It is used to create an equal pressure under the form, preventing it from being crushed.

Pressure bag moulding

This process is related to vacuum bag moulding in exactly the same way as it sounds. A solid female mould is used along with a flexible male mould. The reinforcement is placed inside the female mould with just enough resin to allow the fabric to stick in place (wet lay up). A measured amount of resin is then liberally brushed indiscriminately into the mould and the mould is then clamped to a machine that contains the male flexible mould. The flexible male membrane is then inflated with heated compressed air or possibly steam. The female mould can also be heated. Excess resin is forced out along with trapped air. This process is extensively used in the production of composite helmets due to the lower cost of unskilled labor. Cycle times for a helmet bag moulding machine vary from 20 to 45 minutes, but the finished shells require no further curing if the moulds are heated.

Autoclave moulding

A process using a two-sided mould set that forms both surfaces of the panel. On the lower side is a rigid mould and on the upper side is a flexible membrane made from silicone or an extruded polymer film such as nylon. Reinforcement materials can be placed manually or robotically. They include continuous fibre forms fashioned into textile constructions. Most often, they are pre-impregnated with the resin in the form of prepreg fabrics or unidirectional tapes. In some instances, a resin film is placed upon the lower mould and dry reinforcement is placed above. The upper mould is installed and vacuum is applied to the mould cavity. The assembly is placed into an autoclave. This process is generally performed at both elevated pressure and elevated temperature. The use of elevated pressure facilitates a high fibre volume fraction and low void content for maximum structural efficiency.

Resin transfer moulding (RTM)

A process using a two-sided mould set that forms both surfaces of the panel. The lower side is a rigid mould. The upper side can be a rigid or flexible mould. Flexible moulds can be made from composite materials, silicone or extruded polymer films such as nylon. The two sides fit together to produce a mould cavity. The distinguishing feature of resin transfer moulding is that the reinforcement materials are placed into this cavity and the mould set is closed prior to the introduction of matrix material. Resin transfer moulding includes numerous varieties which differ in the mechanics of how the resin is introduced to the reinforcement in the mould cavity. These variations include everything from vacuum infusion (for resin infusion see also boat building) to vacuum assisted resin transfer moulding (VARTM). This process can be performed at either ambient or elevated temperature.

Other

Other types of moulding include press moulding, transfer moulding, pultrusion moulding, filament winding, casting, centrifugal casting and continuous casting. There are also forming capabilities including CNC filament winding, vacuum infusion, wet lay-up, compression moulding, and thermoplastic moulding, to name a few. The use of curing ovens and paint booths is also needed for some projects.

Tooling

Some types of tooling materials used in the manufacturing of composites structures include invar, steel, aluminium, reinforced silicone rubber, nickel, and carbon fibre. Selection of the tooling material is typically based on, but not limited to, the coefficient of thermal expansion, expected number of cycles, end item tolerance, desired or required surface condition, method of cure, glass transition temperature of the material being moulded, moulding method, matrix, cost and a variety of other considerations.

Properties

Mechanics

The physical properties of composite materials are generally not isotropic (independent of direction of applied force) in nature, but rather are typically orthotropic (different depending on the direction of the applied force or load). For instance, the stiffness of a composite panel will often depend upon the orientation of the applied forces and/or moments. Panel stiffness is also dependent on the design of the panel. For instance, the fibre reinforcement and matrix used, the method of panel build, thermoset versus thermoplastic, type of weave, and orientation of fibre axis to the primary force.

In contrast, isotropic materials (for example, aluminium or steel), in standard wrought forms, typically have the same stiffness regardless of the directional orientation of the applied forces and/or moments.

The relationship between forces/moments and strains/curvatures for an isotropic material can be described with the following material properties: Young's Modulus, the shear Modulus and the Poisson's ratio, in relatively simple mathematical relationships. For the anisotropic material, it requires the mathematics of a second order tensor and up to 21 material property constants. For the special case of orthogonal isotropy, there are three different material property constants for each of Young's Modulus, Shear Modulus and Poisson's ratio—a total of 9 constants to describe the relationship between forces/moments and strains/curvatures.

Techniques that take advantage of the anisotropic properties of the materials include mortise and tenon joints (in natural composites such as wood) and Pi Joints in synthetic composites.

Resins

Typically, most common composite materials, including fiberglass, carbon fiber, and Kevlar, include at least two parts, the substrate and the resin.

Polyester resin tends to have yellowish tint, and is suitable for most backyard projects. Its weaknesses are that it is UV sensitive and can tend to degrade over time, and thus generally is also coated to help preserve it. It is often used in the making of surfboards and for marine applications. Its hardener is a MEKP, and is mixed at 14 drops per oz. MEKP is composed of methyl ethyl ketone peroxide, a catalyst. When MEKP is mixed with the resin, the resulting chemical reaction causes heat to build up and cure or harden the resin.

Vinylester resin tends to have a purplish to bluish to greenish tint. This resin has lower viscosity than polyester resin, and is more transparent. This resin is often billed as being fuel resistant, but will melt in contact with gasoline. This resin tends to be more resistant over time to degradation than polyester resin, and is more flexible. It uses the same hardener as polyester resin (at the same mix ratio) and the cost is approximately the same.

Epoxy resin is almost totally transparent when cured. In the aerospace industry, epoxy is used as a structural matrix material or as a structural glue.

Shape memory polymer (SMP) resins have varying visual characteristics depending on their formulation. These resins may be epoxy-based, which can be used for auto body and outdoor equipment repairs; cyanate-ester-based, which are used in space applications; and acrylate-based, which can be used in very cold temperature applications, such as for sensors that indicate whether perishable goods have warmed above a certain maximum temperature. These resins are unique in that their shape can be repeatedly changed by heating above their glass transition temperature (T_g). When heated, they become flexible and elastic, allowing for easy configuration. Once they are cooled, they will maintain their new shape. The resins will return to their original shapes when they are reheated above their T_g. The advantage of shape memory polymer resins is that they can be shaped and reshaped repeatedly without losing their material properties, and these resins can be used in fabricating shape memory composites.

Categories of fiber-reinforced composite materials

Typologies of fibre-reinforced composite materials:

a) continuous fibre-reinforced
b) discontinuous aligned fibre-reinforced
c) discontinuous random-oriented fibre-reinforced.

Fiber-reinforced composite materials can be divided into two main categories normally referred to as short fiber-reinforced materials and continuous fiber-reinforced materials. Continuous reinforced materials will often constitute a layered or laminated structure. The woven and continuous fibre styles are typically available in a variety of forms, being pre-impregnated with the given matrix (resin), dry, uni-directional tapes of various widths, plain weave, harness satins, braided, and stitched.

The short and long fibers are typically employed in compression moulding and sheet moulding operations. These come in the form of flakes, chips, and random mate (which can also be made from a continuous fibre laid in random fashion until the desired thickness of the ply / laminate is achieved).

Failure

Shock, impact, or repeated cyclic stresses can cause the laminate to separate at the interface between two layers, a condition known as delamination. Individual fibres can separate from the matrix e.g. fibre pull-out.

Composites can fail on the microscopic or macroscopic scale. Compression failures can occur at both the macro scale or at each individual reinforcing fibre in compression buckling. Tension failures can be net section failures of the part or degradation of the composite at a microscopic scale where one or more of the layers in the composite fail in tension of the matrix or failure the bond between the matrix and fibres.

Some composites are brittle and have little reserve strength beyond the initial onset of failure while others may have large deformations and have reserve energy absorbing capacity past the onset of damage. The variations in fibres and matrices that are available and the mixtures that can be made with blends leave a very broad range of properties that can be designed into a composite structure. The best known failure of a brittle ceramic matrix composite occurred when the carbon-carbon composite tile on the leading edge of the wing of the Space Shuttle Columbia fractured when impacted during take-off. It led to catastrophic break-up of the vehicle when it re-entered the Earth's atmosphere on 1 February 2003.

Compared to metals, composites have relatively poor bearing strength.

Testing

To aid in predicting and preventing failures, composites are tested before and after construction. Pre-construction testing may use finite element analysis (FEA) for ply-by-ply analysis of curved surfaces and predicting wrinkling, crimping and dimpling of composites. Materials may be tested after construction through several nondestructive methods including ultrasonics, thermography, shearography and X-ray radiography^.

Examples

Materials

Fibre-reinforced polymers or FRPs include wood (comprising cellulose fibres in a lignin and hemicellulose matrix), carbon-fibre reinforced plastic or CFRP, and glass-reinforced plastic or GRP. If classified by matrix then there are thermoplastic composites, short fibre thermoplastics, long fibre thermoplastics or long fibre-reinforced thermoplastics. There are numerous thermoset composites, but advanced systems usually incorporate aramid fibre and carbon fibre in an epoxy resin matrix.

Shape memory polymer composites are high-performance composites, formulated using fibre or fabric reinforcement and shape memory polymer resin as the matrix. Since a shape memory polymer resin is used as the matrix, these composites have the ability to be easily manipulated into various configurations when they are heated above their activation temperatures and will exhibit high strength and stiffness at lower temperatures. They can also be reheated and reshaped repeatedly without losing their material properties. These composites are ideal for applications such as lightweight, rigid, deployable structures; rapid manufacturing; and dynamic reinforcement.

Composites can also use metal fibres reinforcing other metals, as in metal matrix composites or MMC. The benefit of magnesium is that it does not degrade in outer space. Ceramic matrix composites include bone (hydroxyapatite reinforced with collagen fibres), Cermet (ceramic and metal) and concrete. Ceramic matrix composites are built primarily for fracture toughness, not for strength. Organic matrix/ceramic aggregate composites include asphalt concrete, mastic asphalt, mastic roller hybrid, dental composite, syntactic foam and mother of pearl. Chobham armour is a special type of composite armour used in military applications.

Additionally, thermoplastic composite materials can be formulated with specific metal powders resulting in materials with a density range from 2 g/cm³ to 11 g/cm³ (same density as lead). The most common name for this type of material is High Gravity Compound (HGC), although Lead Replacement is also used. These materials can be used in place of traditional materials such as aluminium, stainless steel, brass, bronze, copper, lead, and even tungsten in weighting, balancing (for example, modifying the centre of gravity of a tennis racquet), vibration dampening, and radiation shielding applications. High density composites are an economically viable option when certain materials are deemed hazardous and are banned (such as lead) or when secondary operations costs (such as machining, finishing, or coating) are a factor.

Engineered wood includes a wide variety of different products such as wood fibre board, plywood, oriented strand board, wood plastic composite (recycled wood fibre in polyethylene matrix), Pykrete (sawdust in ice matrix), Plastic-impregnated or laminated paper or textiles, Arborite, Formica (plastic) and Micarta. Other engineered laminate composites, such as Mallite, use a central core of end grain balsa wood, bonded to surface skins of light alloy or GRP. These generate low-weight, high rigidity materials.

Products

Composite materials have gained popularity (despite their generally high cost) in high-performance products that need to be lightweight, yet strong enough to take harsh loading conditions such as aerospace components (tails, wings, fuselages, propellers), boat and scull hulls, bicycle frames and racing car bodies. Other uses include fishing rods, storage tanks, and baseball bats. The new Boeing 787 structure including the wings and fuselage is composed largely of composites. Composite materials are also becoming more common in the realm of orthopedic surgery.

Carbon composite is a key material in today's launch vehicles and heat shields for the re-entry phase of spacecraft. It is widely used in solar panel substrates, antenna reflectors and yokes of spacecraft. It is also used in payload adapters, inter-stage structures and heat shields of launch vehicles. Furthermore disk brake systems of airplanes and racing cars are using carbon/carbon material, and the composite material with carbon fibers and silicon carbide matrix has been introduced in luxury vehicles and sports cars.

In 2007, an all-composite military Humvee was introduced by TPI Composites Inc and Armor Holdings Inc, the first all-composite military vehicle. By using composites the vehicle is lighter, allowing higher payloads. In 2008, carbon fiber and DuPont Kevlar (five times stronger than steel) were combined with enhanced thermoset resins to make military transit cases by ECS Composites creating 30-percent lighter cases with high strength.

Many composite layup designs also include a co-curing or post-curing of the prepreg with various other mediums, such as honeycomb or foam. This is commonly called a sandwich structure. This is a more common layup process for the manufacture of radomes, doors, cowlings, or non-structural parts. The finishing of the composite parts is also critical in the final design. Many of these finishes will include rain-erosion coatings or polyurethane coatings.

Characterization (materials science)

Characterization, when used in materials science, refers to the use of external techniques to probe into the internal structure and properties of a material. Characterization can take the form of actual materials testing, or analysis, for example in some form of microscope.
Analysis techniques are used simply to magnify the specimen, to visualize its internal structure, and to gain knowledge as to the distribution of elements within the specimen and their interactions.
Magnification and internal visualisation are normally done in a type of microscope, such as:

• Optical Microscope
• Scanning Electron Microscope (SEM)
• Transmission Electron Microscope (TEM)
• Field Ion Microscope (FIM)
• Scanning Tunneling Microscope (STM)
• Atomic Force Microscope (AFM)

Elemental analysis of the specimen can also be done in a number of ways:

• Energy-Dispersive X-ray spectroscopy (EDX)
• Wavelength Dispersive X-ray spectroscopy (WDX)
• Mass spectrometry
• Impulse excitation technique (IET)
• Secondary Ion Mass Spectrometry (SIMS)
• Electron Energy Loss Spectroscopy (EELS)
• Auger electron spectroscopy
• X-ray photoelectron spectroscopy (XPS)